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DOI | 10.1002/MASY.201150613 | ||||
Año | 2011 | ||||
Tipo | proceedings paper |
Citas Totales
Autores Afiliación Chile
Instituciones Chile
% Participación
Internacional
Autores
Afiliación Extranjera
Instituciones
Extranjeras
This paper describes the electrochemical reduction of nitrite ion in 0.1M NaClO4, on glassy carbon or ITO electrodes modified with mixtures PVC-tetraruthenated metalloporphyrins. This electrode is able to keep the extraordinary electrocatalytic properties of the macrocycle allowing multielectronic transfers and a great stability as a consequence of the inclusion of the macrocycles into a polymeric support such as PVC. On the other hand, the electrochemical reduction of nitrite ion on these modified electrodes studied by cyclic voltammetry shows an enhancement in the current values and lower overpotential compared with the activity of the bare glassy carbon electrode. Controlled potential electrolysis experiments verify the production of ammonia, hydrazine and hydroxylamine, showing the electrocatalytic character and the stability of this modified electrode.
Ord. | Autor | Género | Institución - País |
---|---|---|---|
1 | Calfuman, Karla | Mujer |
Universidad de Chile - Chile
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2 | DREYSE-SILVA, PAULINA ANDREA | Mujer |
Universidad de Chile - Chile
|
3 | GARCIA-SANHUEZA, CAMILO ANDRES | Hombre |
Universidad de Chile - Chile
|
4 | Aguirre, Maria J. | Mujer |
Universidad de Santiago de Chile - Chile
|
5 | Beltran, Tomas | Hombre |
Univ Jaume 1 - España
Universidad Jaume I - España |
6 | Guillamon, Eva | - |
Univ Jaume 1 - España
Universidad Jaume I - España |
7 | Sorribes, Ivan | Hombre |
Univ Jaume 1 - España
Universidad Jaume I - España |
8 | Vicent, Cristian | Hombre |
Univ Jaume 1 - España
Universidad Jaume I - España |
9 | Llusar, Rosa | Mujer |
Univ Jaume 1 - España
Universidad Jaume I - España |
10 | Isaacs, Mauricio | Hombre |
Universidad de Chile - Chile
|
11 | Costamagna, J | - | |
12 | Rabagliati, FM | - | |
13 | Rivas, BL | - |